The first examples of discotic liquid crystalline gemini surfactants

Six novel gemini imidazolium salts tethered with hexaalkoxytriphenylene moieties were prepared by quaternization of imidazole nitrogen with co-bromo-substitutecl triphenylene derivatives. Their chemical structures were examined by H-1 NMR, IR, UV, MS, and elemental analyses. The mesomorphic properties of these discotic dimeric salts were investigated by polarizing optical microscopy, differential scanning calorimetry, and X-ray diffraction studies. These triphenylene-imidazole-based gemini dimers with bromide as counter ion were found to exhibit liquid crystalline behavior over a wide temperature range and display ionic conductivity in the range of 10(-6) to 10(-5) S/m. These materials tend to form monolayer at the air-water interface. 2010 Elsevier Ltd. All rights reserved,