4.4 Article

Gold-catalyzed glycosidations: synthesis of 1,6-anhydro saccharides

Journal

TETRAHEDRON LETTERS
Volume 51, Issue 45, Pages 5912-5914

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.09.004

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Funding

  1. CSIR [NWP0036-B]
  2. CSIR, New Delhi

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Various 1,6-anhydro sugars are synthesized utilizing salient features of gold-catalyzed glycosidations. All the reactions occurred under mild conditions in the presence of 7 mol % of AuBr3 enabling easy synthesis of 1,6-anhydro sugars from corresponding 6-hydroxy propargyl/methyl monosaccharides, disaccharides, and trisaccharides in good yields. (C) 2010 Elsevier Ltd. All rights reserved.

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