Journal
TETRAHEDRON LETTERS
Volume 51, Issue 31, Pages 4107-4109Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.05.140
Keywords
Organosilanes; Electrophilic substitution; Carbocation; Dendritic molecule
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Funding
- MEXT, Japan
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [21750039] Funding Source: KAKEN
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A highly efficient electrochemical method for synthesis of halosilanes bearing bulky substituents was developed. Electrophilic multiple substitution on tris(diphenylmethyl)silane with diarylcarbenium ions afforded a highly sterically demanding hydrosilane, tris(extended diarylmethyl)silane (TEDAMS-H), which was converted to the corresponding bromosilane (TEDAMS-Br). (C) 2010 Elsevier Ltd. All rights reserved.
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