Journal
TETRAHEDRON LETTERS
Volume 51, Issue 5, Pages 860-862Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.12.034
Keywords
Isoindolones; Indium; Barbier reaction; Double allylation; ortho-Cyanobenzoates
Categories
Funding
- Ministry of Education, Science and Technology [2009-0070633]
- National Research Foundation of Korea [2009-0070633] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Various 3,3-diallyl isoindolones were synthesized via a indium-mediated Barbier type double allylation reaction of ortho-cyanobenzoates in good yields in short time. The reactivity of nitrile group toward allylindium is sufficient to form a cyclic compound when a suitable electrophilic center is present in the same molecule to trap the imine intermediate. (c) 2009 Elsevier Ltd. All rights reserved.
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