Journal
TETRAHEDRON LETTERS
Volume 51, Issue 38, Pages 5064-5067Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.07.105
Keywords
Aqueous metathesis; Reversible metathesis; Dynamic combinatorial chemistry; Allyl sulfides
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Funding
- ARC [DP0984695]
- Australian Research Council [DP0984695] Funding Source: Australian Research Council
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Solutions of heterocycles having an allyl sulfide unit and simple alkenes in 50% t-BuOH/H2O undergo reversible olefin metathesis reactions with the second generation Hoveyda-Grubbs catalyst. The choice of functional groups is limited by competitive chelation of some heterocycles with the catalyst, and other stereoelectronic effects. (C) 2010 Elsevier Ltd. All rights reserved.
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