Journal
TETRAHEDRON LETTERS
Volume 51, Issue 21, Pages 2810-2812Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.03.067
Keywords
Catalysis; Suzuki-Miyaura reaction; Site-selectivity; Palladium; Organofluorine compounds
Categories
Funding
- DAAD
- University of Rostock
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The Suzuki-Miyaura reaction of 1,4-dibromo-2-fluorobenzene with two equivalents of arylboronic acids gave fluorinated paro-terphenyls. The reaction with 1 equiv of arylboronic acid resulted in site-selective formation of biphenyls. The one-pot reaction of 1,4-dibromo-2-fluorobenzene with two different arylboronic acids afforded fluorinated para-terphenyls containing two different terminal aryl groups. (C) 2010 Elsevier Ltd. All rights reserved.
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