Journal
TETRAHEDRON LETTERS
Volume 51, Issue 37, Pages 4870-4873Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.07.042
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Funding
- National Natural Science Foundation of China [20802075]
- Chinese Academy of Sciences
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A series of secondary amine-thiourea catalysts derived from L-proline and chiral diamine were prepared and successfully applied to the highly effective and enantioselective alpha-amination of unmodified aldehydes with various azodicarboxylates in excellent yields (up to 99%) and enantioselectivities (up to 99% ee) within a few minutes. (C) 2010 Elsevier Ltd. All rights reserved.
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