Journal
TETRAHEDRON LETTERS
Volume 51, Issue 46, Pages 6025-6027Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.09.032
Keywords
Rumphella antipathies; Rumphellaone; Caryophyllane
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Funding
- National Museum of Marine Biology and Aquarium [99200321, 99200322]
- National Dong Hwa University
- Asia-Pacific Ocean Research Center, National Sun Yat-sen University [97C031702]
- National Science Council, Taiwan [NSC 98-2323-B-291-001, 99-2323-B-291-001, 98-2320-B-291-001-MY3]
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A novel 4,5-seco-caryophyllane sesquiterpenoid derivative, rumphellaone A (1), which was found to possess an unprecedented gamma-lactone moiety, was isolated from the gorgonian coral Rumphella antipathies. The structure of 1 was elucidated by spectroscopic method. A plausible biosynthetic pathway of compound 1 was proposed. (C) 2010 Elsevier Ltd. All rights reserved.
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