Journal
TETRAHEDRON LETTERS
Volume 50, Issue 24, Pages 2973-2975Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.04.007
Keywords
Palladium; Nitrite; Hydration; Amide; Acetaldoxime
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Funding
- Korean Government [KRF-2008-313-C00487]
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An efficient palladium-catalyzed protocol for the hydration of nitrile to amide with acetaldoxime has been developed. A plausible mechanism was suggested involving the first Pd(II)-catalyzed nitrile-oxime coupling and the following disruption of the intermediate into amide and acetonitrile in a concerted manner. (C) 2009 Elsevier Ltd. All rights reserved.
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