Journal
TETRAHEDRON LETTERS
Volume 50, Issue 6, Pages 688-692Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.11.101
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Funding
- DJM [EP/D031168/1]
- Coordenacao de Aperfeicoamento de Pessoal de Ensinol Superior (CAPES, Brazil)
- EPSRC [EP/F019424/1, EP/D031168/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F019424/1] Funding Source: researchfish
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The combination of an enantiomerically pure N'-alkylated derivative of N-4-toluenesulfonyl-1,2-diphenylethane-1,2-diamine (TsDPEN) with iridium trichloride results in the formation of a catalyst with high selectivity for ketone hydrogenation. Products with enantiomeric excesses of up to 84% were formed. The best results were obtained using a ligand with an n-alkyl chain and ortho-substituted acetophenone derivatives and other hindered derivatives. (C) 2008 Elsevier Ltd. All rights reserved.
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