Journal
TETRAHEDRON LETTERS
Volume 50, Issue 39, Pages 5523-5528Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.07.076
Keywords
C-S coupling; CuI; Catechol violet; Diaryl sulfides; Vinyl thioethers
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Funding
- Department of Science & Technology, New Delhi [SR/S1/OC-49/2006]
- CSIR, New Delhi
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Combination of CuI and Catechol violet (CuI-CV) was employed as catalyst for the first time in the C-S coupling reaction of a wide variety of aromatic halides, such as aryl iodides, bromo pyridines, activated aryl chlorides, and vinyl iodide with thiols to afford the corresponding thioethers in good to excellent yields. Broad range of functional group tolerance present in both the coupling partners has been observed in this reaction protocol. (C) 2009 Elsevier Ltd. All rights reserved.
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