Journal
TETRAHEDRON LETTERS
Volume 50, Issue 9, Pages 1041-1044Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.12.069
Keywords
Olefin; Photocleavage; Dioxetane; Singlet oxygen
Categories
Funding
- South Dakota Board of Regents
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A series of substituted olefins were tested for their reactivity with singlet oxygen as a singlet oxygen-mediated cleavable linker. Low intensity light of 200 mW/cm(2) was irradiated to the solution of an olefin and 5,10,15-triphenyl-20-(4-hydroxyphenyl)-21H,23H-porphyrin under atmospheric condition, Among the tested olefins, 1,2-cis-diphenoxyethylene reacted fast with singlet oxygen, >80% within 15 min yielding a stoichiometric conversion to aldehyde product without ally side reactions. (C) 2008 Elsevier Ltd. All rights reserved.
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