A highly selective fluorescent chemosensor for silver(I) in water/ethanol mixture

Synthesis, photophysical, and complexation properties of fluorescent chemosensors, L-1 and L-2, with 'receptor-spacer-fluorophore' motif (L-1: NS2O2-cyclic receptor, L-2 : acyclic analogue receptor) are described. Maximum chelation-enhanced fluorescence effect (TURN-ON type) was observed in the presence of Ag+ for both fluoroionophores in a 1:1 (v/v) aqueous ethanol solution: remarkably superior selectivity of L-1 (150-fold) with cyclic receptor than that of the L-2 (50-fold) with acyclic analogue was found. According to the fluorescence and NMR titrations, the excellent selectivity of L-1 is attributed to its topology-based higher affinity in complexation. (C) 2008 Elsevier Ltd. All rights reserved.