Journal
TETRAHEDRON LETTERS
Volume 50, Issue 14, Pages 1603-1606Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.01.101
Keywords
Catalysis; Formic acid; Hydrogen; Ruthenium
Categories
Funding
- State of Mecklenburg-Vorpommern
- BMBF
- DFG (Leibniz-prize)
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The ruthenium-catalyzed generation of hydrogen from formic acid was investigated in the presence of amines and halide additives. While amidines and halide additives increase the production of hydrogen with [RuCl2(p-cyrnene)](2), >330 mL hydrogen/h is generated in the presence of [RuCl2(benzene)](2)/dppe and N,N-dimethyl-n-hexylamine. (C) 2009 Elsevier Ltd. All rights reserved.
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