Journal
TETRAHEDRON LETTERS
Volume 50, Issue 35, Pages 5021-5024Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.06.092
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Funding
- Spanish Ministry of Science and Innovation [AYA2006-15648-C02-01]
- Ministry of Education of the Czech Republic [MSM0021620857]
- ICREA Funding Source: Custom
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A highly enantioselective organocatalytic fluoromalonate addition to alpha,beta-unsaturatecl aldehydes is reported. The reaction is catalyzed by simple and commercially available secondary amines, affording the corresponding 1,4-adducts with high yields and enantioselectivities. (C) 2009 Elsevier Ltd. All rights reserved.
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