Journal
TETRAHEDRON LETTERS
Volume 50, Issue 8, Pages 930-932Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.12.037
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Funding
- NIH [SC2GM082276]
- National Institute of General Medical Sciences
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Reaction of iron(0) carbene complexes with hexafluorobut-2-yne produces 3,4-bis(trifluoromethylated)furans in a process that is favored for electron-rich carbenes. No traces of furannulation or benzannulation are observed with Group 6 Fischer carbenes. Reaction of hexafluorobut-2-yne with a vinylketene iron(0) complex gives a 2,3-bis-trifluoromethylated phenol. (C) 2008 Elsevier Ltd. All rights reserved.
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