Journal
TETRAHEDRON LETTERS
Volume 50, Issue 33, Pages 4773-4776Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.06.040
Keywords
The Meyer-Schuster rearrangement; Propargylic aryl carbinols; alpha,beta-Unsaturated carbonyl compounds; Indium(III) chloride; MW-assisted synthesis; Water as solvent; Isomerization reactions
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Funding
- Ministerio de Ciencia e Innovacion (MICINN) [CTQ2006-08485/BQU]
- Consolider Ingenio 2010 [CSD2007-00006]
- Gobierno del Principado de Asturias
- FICYT [IB08-036]
- European Social Fund
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A novel, efficient, simple and environmentally benign protocol for the Meyer-Schuster isomerization of propargylic aryl carbinols into of alpha,beta-unsaturated carbonyl compounds has been developed using catalytic amounts of InCl3 pure water as the solvent, and microwave irradiation as the heating source. (C) 2009 Elsevier Ltd. All rights reserved.
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