Journal
TETRAHEDRON LETTERS
Volume 50, Issue 26, Pages 3478-3481Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.03.005
Keywords
2,2 '-Bipyridine; Arylboronic acids; N-Tosylarylaldimine; Addition; Asymmetric version; Palladium
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Funding
- Major State Basic Research Program [2006CB806105]
- National Natural Sciences Foundation of China [20423001, 20732005]
- Chinese Academy of Sciences
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A Pd(II)/NO2-bpy-catalyzed addition of the arylboronic acids to N-tosylaldimines to yield diarylmethylamines with moderate to excellent yield was developed. The use of bipyridines as the ligands is crucial in this reaction. The asymmetric version of the reaction also showed that a moderate high yield and ee value can be obtained using the pymox ligands. (C) 2009 Elsevier Ltd. All rights reserved.
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