Journal
TETRAHEDRON LETTERS
Volume 50, Issue 40, Pages 5602-5604Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.07.071
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Funding
- Global COE Program
- Chemistry Innovation through Cooperation of Science and Engineering
- MEXT, Japan
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The asymmetric Friedel-Crafts-type alkylation in aqueous media was realized by the resin-supported N-terminal prolyl peptide catalyst having a polyleucine tether. The hydrophobic polyleucine chain in the peptide catalyst was essential for the reaction efficiency and enantioselectivity. The resin-bound peptide catalyst could be reused at least for five times. (C) 2009 Elsevier Ltd. All rights reserved.
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