Journal
TETRAHEDRON LETTERS
Volume 50, Issue 38, Pages 5344-5346Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.07.011
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Funding
- EPSRC
- GlaxoSmithKline
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The oxo-imido molybdenum complex 2a is an effective catalyst at low catalyst loadings (0.5 mol% or below) for the epoxidation of a range of alkenes with (BuOOH)-Bu-t in PhMe at 90 degrees C. Reactions are complete in less than 4 h and the products are isolated in high yields. The catalytic system is chemoselective for the epoxidation of electron-rich alkenes and allylic alcohols. (C) 2009 Elsevier Ltd. All rights reserved.
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