Journal
TETRAHEDRON LETTERS
Volume 50, Issue 15, Pages 1677-1680Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.01.077
Keywords
Aerobic oxidation; Hydrocarbons; Xanthone; Nitroxyl radical; Quaternary ammonium salts
Categories
Funding
- Natural Science Foundation of China [20672111, 20736010]
- Chinese Academy of Sciences [DICP K2007D6]
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A nonmetal catalytic system consisting of N-hydroxyphthalimide, xanthone, and tetramethylammonium chloride was developed. A wide range of hydrocarbons could be oxidized efficiently with dioxygen under mild conditions. In the presence of xanthone and tetramethylammonium chloride, catalytic activity of N-hydroxyphthalimide was greatly improved, and selectivity for alkyl hydroperoxide was remarkably decreased. (C) 2009 Published by Elsevier Ltd.
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