Journal
TETRAHEDRON LETTERS
Volume 50, Issue 4, Pages 480-483Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.11.047
Keywords
beta-Mercapto alcohol; O-Acrylation; Alkoxy tin; Chemoselective acrylation
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Funding
- Pusan National University
- MKE/IITA, Korea. [2006-S-073-02]
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Chemoselective preparation of O-acylated derivatives from bis-protected mercapto alcohols was described. Trialkylsilyl and trialkylstannyl chloride are used to generate an intermediate with O- and S-protection. The intermediates from beta-mercapto alcohols are reactive toward acylating agents and selective to provide O-acylated derivatives. The present preparation involves the direct conversion of alcohol to the corresponding O-acylated compounds without deprotection. (C) 2008 Elsevier Ltd. All rights reserved.
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