4.4 Article

Hydrogenation of olefins using Hantzsch ester catalyzed by palladium on carbon

Journal

TETRAHEDRON LETTERS
Volume 50, Issue 9, Pages 1026-1028

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.12.062

Keywords

Olefins; alpha,beta-Unsaturated ketones; Hantzsch ester; Palladium on carbon; Hydrogenation; Reduction

Funding

  1. National Natural Science Foundation of China [20702023]
  2. Ministry of Education of China [20070730040]

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Hantzsch 1,4-dihydropyridine (HEH), a well-known model compound of coenzyme NAD(P)H was found as an efficient reducing agent in hydrogenation of unactivated olefins catalyzed by Pd/C. alpha,beta-Unsaturated ketones also underwent hydrogenation, affording the corresponding saturated ketones selectively. (C) 2008 Elsevier Ltd. All rights reserved.

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