Journal
TETRAHEDRON LETTERS
Volume 50, Issue 41, Pages 5744-5747Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.07.140
Keywords
Indium; Barbier reaction; gamma-Ketonitriles; Pyrroles
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Funding
- Korean Government [KRF-2008-313-C00487]
- Korea Basic Science Institute, Gwangju branch
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We developed an efficient synthetic strategy of poly-substituted pyrroles via an indium-mediated Barbier type allylation from gamma-ketonitriles. Initial attack of allylindium species occurred at the nitrile group selectively to form the enamine intermediate, which reacted with the ketone group intramolecularly to furnish the pyrroles. (C) 2009 Elsevier Ltd. All rights reserved.
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