Journal
TETRAHEDRON LETTERS
Volume 50, Issue 26, Pages 3485-3488Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.03.013
Keywords
Vinylogous Mukaiyama aldol; Polyketides; Oxazaborolidines; Natural products; Enantioselective
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The synthesis of polyketide segments through the vinylogous Mukaiyama aldol reaction is reported. The use of chiral oxazaborolidines allows using terminal substituted ketene acetals and provides access to extended segments and two new chiral centers. (C) 2009 Elsevier Ltd. All rights reserved.
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