Journal
TETRAHEDRON LETTERS
Volume 50, Issue 45, Pages 6106-6109Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.08.042
Keywords
Benzoxazole; Hydrogen transfer; Oxidation; Catalysis
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Funding
- EPSRC [EP/F038321/1, EP/F0376431/1]
- Royal Society Industry Fellow
- EPSRC [EP/F038321/1, EP/F037643/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F037643/1, EP/F038321/1] Funding Source: researchfish
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Benzoxazoles are synthesised directly by oxidative condensation of primary and secondary amines with o-aminophenols under hydrogen transfer catalysis. The optimal system utilises 1 mol % of the Shvo catalyst, with dimethoxybenzoquinone as the hydrogen-accepting terminal oxidant. (C) 2009 Elsevier Ltd. All rights reserved.
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