4.4 Article

Novel polymers of intrinsic microporosity (PIMs) derived from 1,1-spiro-bis(1,2,3,4-tetrahydronaphthalene)-based monomers

Journal

TETRAHEDRON LETTERS
Volume 50, Issue 43, Pages 5954-5957

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.08.032

Keywords

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Funding

  1. EPSRC [G01244X, D074312]
  2. EPSRC [EP/G01244X/1] Funding Source: UKRI
  3. Engineering and Physical Sciences Research Council [EP/G01244X/1] Funding Source: researchfish

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The synthesis of novel monomers based upon the rigid 1,1'-spiro-bis(1,2,4,5-tetrahydro-6,7-dihydroxynaphthalene) framework is reported. These monomers can be used for the synthesis of polymers of intrinsic microporosity (PIMs) due to their reactive catechol units and nonlinear shape, which introduces the necessary sites of contortion into the resulting PIM. (C) 2009 Elsevier Ltd. All rights reserved.

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