Journal
TETRAHEDRON LETTERS
Volume 50, Issue 49, Pages 6800-6802Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.09.115
Keywords
Lossen rearrangement; Cyanuric chloride; Hydroxamic acids; Isocyanates
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An efficient method for the Lossen rearrangement that uses 2,4,6-trichloro-1,3,5-triazine (TCT) as a promoter is reported. This procedure allowed the preparation of various carbamates, thiocarbamates, and ureas in good yields directly from the corresponding hydroxamic acids. (C) 2009 Elsevier Ltd. All rights reserved.
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