Journal
TETRAHEDRON LETTERS
Volume 50, Issue 48, Pages 6631-6634Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.09.025
Keywords
Iodine; Allylation; Lactols; C-Allylfuranosides
Categories
Funding
- CSIR, New Delhi
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Lactols and their ethers undergo smooth allylation with allyltrimethylsilane in the presence of 5 mol % iodine in dichloromethane at -78 degrees C to afford C-allylfuranosides in good yields and with high diastereoselectivity. The use of iodine makes this method simple, convenient and practical. This is the first report on the allylation of lactols with allyltrimethylsilane using molecular iodine as a catalyst. Enhanced diastereoselectivity is the key feature of this protocol. (C) 2009 Elsevier Ltd. All rights reserved.
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