Journal
TETRAHEDRON LETTERS
Volume 50, Issue 14, Pages 1653-1657Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.01.123
Keywords
Ionic liquid; Aza-Michael addition; Aza-conjugate addition; Aliphatic amines; Aromatic amines
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Funding
- National Natural Science Foundation of China [20776127]
- National Key Technology RD Program [2007BA1341307]
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A task-specific ionic liquid, 1,8-diazabicyclo[5.4.0]-undec-7-en-8-ium acetate has been successfully used as a catalyst for aza-conjugate addition of aliphatic or aromatic amines to various electron deficient alkenes under solvent-free conditions and at room temperature. The catalyst can be reused for six times without noticeable loss of activity. (C) 2009 Elsevier Ltd. All rights reserved.
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