Journal
TETRAHEDRON LETTERS
Volume 50, Issue 12, Pages 1328-1330Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.01.024
Keywords
Sphingolipids; Asymmetric synthesis; Asymmetric Henry reaction; Hydrolytic kinetic resolution; Regioselective ring opening
Categories
Funding
- CSIR
- UGC, New Delhi
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A short and efficient synthesis of 1-deoxy-5-hydroxy sphingolipid is described. The key steps involved are a Jacobsen hydrolytic kinetic resolution (HKR) and Shibasaki's asymmetric Henry reaction. (C) 2009 Elsevier Ltd. All rights reserved.
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