4.4 Article

TiCl3OTf-[bmim]Br: a novel and efficient catalyst system for chemoselective one-pot synthesis of thioamides from arylaldoximes

Journal

TETRAHEDRON LETTERS
Volume 49, Issue 49, Pages 6969-6971

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.09.084

Keywords

Thioamides; Oximes; One-pot reaction; Chemoselectivity; TiCl3OTf-[bmim]Br; Ionic liquid

Funding

  1. 'Center of Excellence of Chemistry of University of Isfahan' (CECUI)
  2. Council of the University of Isfahan

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The combination of TiCl3OTf with 1-butyl-3-methylimidazolium bromide is found to be at) efficient and novel catalytic system for chemoselective one-pot transformation of arylaldoximes to their corresponding thioamides in high to excellent yields. (C) 2008 Elsevier Ltd. All rights reserved.

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