Journal
TETRAHEDRON LETTERS
Volume 49, Issue 43, Pages 6262-6264Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.08.042
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A new class of chiral phosphinothioureas has been developed as efficient organocatalyst for the enantioselective Morita-Baylis-Hillman reaction of aromatic aldehydes with methyl vinyl ketone. The reaction proceeds under very mild conditions to afford the desired product in a short time period in good to excellent yields with up to 94% ee. (C) 2008 Elsevier Ltd. All rights reserved.
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