Journal
TETRAHEDRON LETTERS
Volume 49, Issue 6, Pages 965-969Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.12.023
Keywords
water-soluble catalyst; imines; hydrogenation; biphasic catalysis
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Direct reductive amination of aliphatic, aromatic and heterocyclic carbonyl compounds with primary/secondary amines is reported with water-soluble Fe(II)/EDTA complex as a catalyst using low-pressure molecular hydrogen in a biphasic media. The catalyst is highly selective, recyclable and is an excellent replacement for expensive noble metal catalysts or stoichiometric reducing agents. (c) 2007 Elsevier Ltd. All rights reserved.
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