4.4 Article

Highly efficient catalytic system for hydrosilylation of ketones with iron(II) acetate-thiophenecarboxylate

Journal

TETRAHEDRON LETTERS
Volume 49, Issue 1, Pages 110-113

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.11.002

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A combination of a catalyst derived from ferrous acetate and sodium thiophene-2-carboxylate efficiently promoted hydrosilylation of aromatic and aliphatic ketones to give the corresponding secondary alcohols in high yields with extremely high selectivity. (C) 2007 Elsevier Ltd. All rights reserved.

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