Journal
TETRAHEDRON LETTERS
Volume 49, Issue 33, Pages 4865-4868Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.06.014
Keywords
oxidative kinetic resolution; secondary alcohol; Mn(III) salen; mesoporous silica SBA-15; supported ionic liquid
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A supported ionic liquid strategy has been applied for the immobilization of a chiral Mn(III) salen complex onto ionic liquid modified mesoporous silica SBA-15. The immobilized catalyst demonstrated high enantioselectivity and activity in the oxidative kinetic resolution of secondary alcohols, and could be recycled five times without obvious loss of activity. (C) 2008 Elsevier Ltd. All rights reserved.
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