Journal
TETRAHEDRON LETTERS
Volume 49, Issue 25, Pages 3991-3994Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.04.093
Keywords
allylation; enaminone; beta-keto allyl enamides; ketene N,S-acetal
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Regioselective allylation of enaminones using CuCl2 as the catalyst to give C-allylated products is reported for the first time. The C-allylated products undergo hydrolysis followed by a rearrangement yielding beta-keto allyl enamides in excellent yields. (C) 2008 Elsevier Ltd. All rights reserved.
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