Journal
TETRAHEDRON LETTERS
Volume 49, Issue 17, Pages 2714-2718Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.02.163
Keywords
acetal; acetate; acetonide; homogeneous catalysis; protecting groups
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The transformation of acetonides into the corresponding diacetates is often required in the synthetic chemistry. An efficient procedure for direct conversion of acetonides into diacetates in the presence of Bi(OTf)(3)center dot xH(2)O under mild conditions has been developed. Primary hydroxyl-acetonides could be selectively transformed into diacetates in the presence of anomeric acetonides and the anomeric acetonides could be tunably converted into 2-acetoxyisopropyl or diacetate groups. (c) 2008 Elsevier Ltd. All rights reserved.
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