Journal
TETRAHEDRON LETTERS
Volume 49, Issue 39, Pages 5625-5628Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.07.053
Keywords
carbonylation; microwave; palladium; aryl chloride; scale-up
Categories
Funding
- Swedish Research Council
- Knut and Alice Wallenberg's Foundation
- Biotage
Ask authors/readers for more resources
Palladium-catalyzed aminocarbonylations of various (hetero)aryl halides with allylamine using Mo(CO)(6) as a solid, in situ CO source, were explored. Microwave-enhanced conditions proved to be highly useful in promoting the conversions in a mere 10-20 min with various (hetero)aryl iodides, bromides and chlorides. The scale-up of a microwave-enhanced aminocarbonylation to 25 mmol scale was performed successfully. (C) 2008 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available