Journal
TETRAHEDRON LETTERS
Volume 49, Issue 33, Pages 4873-4875Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.06.002
Keywords
ruthenium; catalyst; allylic amination; regioselectivity
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The ruthenium-catalyzed highly linear selective allylic amination of monosubstituted allylic acetates with secondary amines was developed. The regioselectivity was controlled by the RU3(CO)(12)/2-DPPBA catalyst, and a linear-type aminated product was obtained as a single regioisomer. (C) 2008 Elsevier Ltd. All rights reserved.
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