Journal
TETRAHEDRON LETTERS
Volume 49, Issue 39, Pages 5662-5663Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.07.080
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Funding
- Air Products and Chemicals, Inc.
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A solution of SF(5)Br in CCl(3)F (0.5-1 M) Was utilized to effect the addition of pentafluorosulfanyl bromide (SF(5)Br) to olefins. The reaction of the SF5Br solution in the presence of triethylborane (0.1 equiv) With an olefin over 20 min at 0 degrees C gave pentafluorosulfanylated compound 2(a-f) in high yield (Table 2). An efficient route for the preparation of synthetically useful SF5-containing esters is also described. (C) 2008 Elsevier Ltd. All rights reserved.
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