Journal
TETRAHEDRON LETTERS
Volume 49, Issue 5, Pages 760-763Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.11.202
Keywords
podophyllotoxin; catalysis; domino; palladium; ring-closure
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A formal synthesis of podophyllotoxin was carried out in nine steps. The key pseudo-domino step was accomplished through the succession of an intermolecular palladium-catalyzed allylic alkylation and an intramolecular Mizoroki-Heck coupling reaction. (C) 2007 Elsevier Ltd. All rights reserved.
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