Journal
TETRAHEDRON LETTERS
Volume 49, Issue 5, Pages 803-807Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.11.196
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Highly enantioselective, amino acid-catalyzed, one-pot three-component asymmetric Mannich reactions between dihydroxyacetone, p-anisidine, and aldehydes are presented. The reactions proceeded with high chemo- and stereoselectivity and furnished the corresponding alpha, alpha'-dihydroxy-beta-aminoketones in high yields with 82-95% ee. (C) 2007 Elsevier Ltd. All rights reserved.
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