Journal
TETRAHEDRON LETTERS
Volume 49, Issue 52, Pages 7419-7422Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.10.073
Keywords
Bolaamphiphile; Synthesis; Supramolecular assemblies; Transmission electron microscopy; Vesicles; Tubules; Hydrogel
Categories
Funding
- Ministere de l'Education Nationale et de la Recherche (France)
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This work presents the synthesis of novel unsymmetrical bolaamphiphiles bearing a sugar residue and a cationic glycine betaine moiety connected to both ends of a C-22 or C-32 oligomethylene bridging chain possessing or not a diacetylenic unit. Preliminary transmission electron microscopy (TEM) studies revealed the polymorphism of these bola lipids with regard to their self-assembled morphologies in water depending on the presence or not of the diacetylenic functionality and on alkyl chain length. (C) 2008 Elsevier Ltd, All rights reserved.
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