Journal
TETRAHEDRON LETTERS
Volume 49, Issue 31, Pages 4610-4612Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.05.086
Keywords
lipase; Corticosteroid; chemoselective alcoholysis; antiandrogen
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Several 17 alpha-monoesters of cortexolone and its Delta(9)-derivative are endowed with antiandrogenic activity. Their synthesis can be accomplished by means of a lipase-catalyzed chemoselective alcoholysis of the corresponding 17 alpha,21-diesters. (c) 2008 Elsevier Ltd. All rights reserved.
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