Journal
TETRAHEDRON LETTERS
Volume 49, Issue 27, Pages 4296-4301Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.04.126
Keywords
heteropoly acids; benzylic/propargylic alcohols; 1,3-dicarbonyls; nucleophilic substitution
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Various 1,3-dicarbonyl compounds reacted readily with benzylic and propargylic alcohols in the presence of 10 mol % of phosphomolybdic acid supported on silica gel (PMA/SiO2) under mild reaction conditions to produce 2-benzylic- and 2-propargylic-1,3-dicarbonyl compounds in excellent yields and with high selectivity. (C) 2008 Elsevier Ltd. All rights reserved.
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