Journal
TETRAHEDRON
Volume 74, Issue 50, Pages 7127-7135Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.09.020
Keywords
Trifluoromethoxylation; Transition metal catalysis; Photoredox catalysis; Fluorine; Radical
Categories
Funding
- NIGMS [R35GM119652]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R35GM119652] Funding Source: NIH RePORTER
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Trifluoromethoxy (OCF3) group exhibits unique properties, which render it a highly desirable structural motif in life and materials sciences. The numbers of newly synthesized trifluoromethyl ethers are booming as new synthetic methods are constantly being developed to access these valuable compounds. This Review summarizes recent catalytic approaches towards preparation of trifluoromethyl ethers. Alkene, allylic, benzylic, and aryl trifluoromethoxylation reactions are discussed herein. (C) 2018 Elsevier Ltd. All rights reserved.
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