Journal
TETRAHEDRON
Volume 70, Issue 21, Pages 3447-3451Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.03.074
Keywords
Cross-dehydrogenative coupling; Copper-catalyzed; Peroxydisulfate; Benzylic ether; Simple carbonyl compound
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Funding
- National Science Foundation of China [21202093]
- Young Scientist Foundation Grant of Shandong Province [BS2013YY001]
- Changjiang Scholars and Innovative Research Team [IRT13028]
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Copper(II) catalyzed cross-dehydrogenative coupling of cyclic benzylic ethers with a variety of simple carbonyl compounds mediated by Na2S2O8 is developed. The scope of carbonyl components is broad, including simple aldehydes as well as ketones. The use of Na2S2O8 as the oxidant for the CDC reaction is attractive based on economical and environmental factors. (C) 2014 Elsevier Ltd. All rights reserved.
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