Journal
TETRAHEDRON
Volume 70, Issue 36, Pages 6100-6105Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.04.034
Keywords
Graphene; PdCu bimetallic nanoparticles; Nitroarenes; Reduction; Aromatic amines
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Funding
- National Natural Science Foundation of China [21272050, 21371044]
- Program for New Century Excellent Talents in University of the Chinese Ministry of Education [NCET-11-0627]
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Graphene supported PdCu bimetallic nanoparticles were synthesized through coreduction of PdCl2 and CuCl2 center dot H2O. X-ray diffraction (XRD), X-ray photoelectron (XPS) and transmission electron microscopy (TEM) were performed to characterize the structures. The complex could be used as an efficient catalyst for reduction of nitroarenes to the corresponding anilines in the presence of NaBH4 and recycled up to six runs without significant loss of activity. (C) 2014 Elsevier Ltd. All rights reserved.
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