Journal
TETRAHEDRON
Volume 70, Issue 27-28, Pages 4270-4278Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.02.045
Keywords
Cyclopropanes; Endoperoxide; Photocatalysis; Photooxygenation; Radical cation
Categories
Funding
- NIH [GM095666]
- Sloan Foundation
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We report that Ru(bpz)(3)(2+) is an excellent sensitizer for the photooxygenation of aryl cyclopropanes upon irradiation with visible light. The effectiveness of this photocatalyst enables the synthesis of a range of five-membered endoperoxides in excellent yield with quite low (0.5 mol %) catalyst loadings even when standard household light sources are utilized. (C) 2014 Elsevier Ltd. All rights reserved.
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